The spontaneous development of spiral waves in the Belousov–Zhabotinsky reaction in the wake of a simple reaction diffusion front is reported in a system for which the redox catalyst is immobilised on an ion-exchange membrane. The behaviour is explained in terms of the concept of vulnerability of the medium.
S. K. Scott, J. D. B. Smith and B. W. Thompson, J. Chem. Soc., Faraday Trans., 1996, 92, 325 DOI: 10.1039/FT9969200325
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