Issue 10, 1992
From the journal:

Journal of the Chemical Society, Dalton Transactions

Salicylideneserinato complexes of vanadium. Crystal structure of the sodium salt of a complex of vanadium-(IV) and -(V)

João Costa Pessoa,   J. Armando L. Silva,   Antonio L. Vieira,   Luís Vilas-Boas,   Paul O'Brien  and  Peter Thornton  

Abstract

A mixed-valence complex of vanadium-(IV) and -(V). Na[V2O3(DL-salser)2]·5H2O (salser =N-salicylideneserinate) has been isolated from solutions containing oxovanadium(IV), DL-serine and salicylaldehyde. Its structure has been determined by X-ray diffraction analysis: space group P21/c, a= 12.845(5), b= 16.615(4), c= 13.072(0)Å, β= 103.53(9)°, Z= 4 and R= 0.0494 for 2860 observed reflections. The V2O33+ unit in this complex has a V–O–V angle smaller than the usual values and each complex ion contains a D- and a L-serine residue. Each sodium ion is surrounded by seven oxygen atoms in a distorted pentagonal-bipyramidal geometry. The magnetic moment and thermogravimetric analysis are also in accord with the structure.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9920001745
Article type
Paper

J. Chem. Soc., Dalton Trans., 1992, 1745-1749

Permissions

Request permissions

Salicylideneserinato complexes of vanadium. Crystal structure of the sodium salt of a complex of vanadium-(IV) and -(V)

J. C. Pessoa, J. A. L. Silva, A. L. Vieira, L. Vilas-Boas, P. O'Brien and P. Thornton, J. Chem. Soc., Dalton Trans., 1992, 1745 DOI: 10.1039/DT9920001745

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements