Issue 10, 1977
From the journal:

Journal of the Chemical Society, Dalton Transactions

The Mössbauer effect in tin(II) compounds. Part 14. Data for some chalcogenide halides

John D. Donaldson,   David R. Laughlin  and  Jack Silver  

Abstract

The 119Sn Mössbauer data for Sn7Br10S2, Sn4Br6Se, and Sn4Br10Te and for compositions from the SnCl2–SnS system are compared with those of the parent halides and chalcogenides. The data for Sn7Br10S2 show the presence of two tin(II) sites but these are not associated with distinct Sn–Br and Sn–S environments. The data for all the phases studied are consistent with random distribution of halide and chalcogenide anions. The variation in Mössbauer parameters of Sn7Br10S2 with temperature and the development of colour in the chalcogenide halides is discussed in terms of direct population of solid-state bands by non-bonding electron pairs.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9770000996
Article type
Paper

J. Chem. Soc., Dalton Trans., 1977, 996-999

Permissions

Request permissions

The Mössbauer effect in tin(II) compounds. Part 14. Data for some chalcogenide halides

J. D. Donaldson, D. R. Laughlin and J. Silver, J. Chem. Soc., Dalton Trans., 1977, 996 DOI: 10.1039/DT9770000996

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements