Issue 1, 1975
From the journal:

Journal of the Chemical Society, Dalton Transactions

Structure and decomposition of a Staudinger reaction intermediate [1-methyl-(or phenyl-)3-tris(dimethylamino)phosphoranylidenetriazene]

Harold Goldwhite,   Peter Gysegem,   Steven Schow  and  Christopher Swyke  

Abstract

Unstable intermediates (Me2N)3PN3R have been isolated from Staudinger reactions between hexamethylphosphorous triamide and methyl or phenyl azides. N.m.r. data strongly support the presence of a linear skeletal P[double bond, length half m-dash]N–N[double bond, length half m-dash]N framework in these compounds. Kinetic studies of the thermal decomposition of the phenyl derivative in methoxybenzene has afforded activation parameters (ΔH‡ 95 KJ mol–1; ΔS‡–40 J mol–1 K–1) indicative of a constrained transition state for this decomposition.

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Article information

DOI
https://doi.org/10.1039/DT9750000016
Article type
Paper

J. Chem. Soc., Dalton Trans., 1975, 16-18

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Structure and decomposition of a Staudinger reaction intermediate [1-methyl-(or phenyl-)3-tris(dimethylamino)phosphoranylidenetriazene]

H. Goldwhite, P. Gysegem, S. Schow and C. Swyke, J. Chem. Soc., Dalton Trans., 1975, 16 DOI: 10.1039/DT9750000016

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