Issue 1, 1973

Crystal structure of µ-(2,2′:6′,2″-terpyridylcadmium)-bis(pentacarbonylmanganese)(2CdMn)

Abstract

Crystals of the title compound are monoclinic with a= 9·158, b= 18·895, c= 16·960 Å, β= 111·38°, Z= 4, space group P21/c. The structure was solved by Patterson and Fourier methods from 3502 visually estimated intensities and refined by least-squares techniques to R 9·11%. The co-ordination of cadmium is very distorted trigonal bipyramidal and there is considerable distortion of the octahedral manganese co-ordination. The molecule has approximate C2 symmetry.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1973, 90-94

Crystal structure of µ-(2,2′:6′,2″-terpyridylcadmium)-bis(pentacarbonylmanganese)(2CdMn)

W. Clegg and P. J. Wheatley, J. Chem. Soc., Dalton Trans., 1973, 90 DOI: 10.1039/DT9730000090

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