Issue 10, 2024

Lignocellulosic full-components hydrogelation using steam-exploded corn stover

Abstract

The fabrication of lignocellulose-based hydrogels typically involves complex modification or dissolution processes using a single component of lignocellulose. However, these processes often have a significant environmental impact, posing challenges to achieving green production of these hydrogels. In this study, we present a non-dissolving strategy to convert whole components of corn stover directly into hydrogel. The central step in this strategy is to expose more functional groups in the corn stover through steam explosion. The exposure of functional groups allowed the steam-exploded corn stover to strengthen the mechanical properties of poly(vinyl alcohol) (PVA) hydrogel by forming more hydrogen bonds with PVA molecules. The tensile strength of the prepared lignocellulose-based hydrogel reached 329.75 kPa, which was 432.69% higher compared to the pure PVA hydrogel. Furthermore, this hydrogel exhibited the advantageous properties of lignin, such as antioxidant and UV resistance capabilities, and was shown to be useful as a sand-fixing agent for large-scale applications. Finally, we verified the universal applicability of the non-solubilizing strategy by preparing similarly shaped hydrogel products from wheat bran and poplar wood flour as well. In summary, our non-dissolving strategy provides a simpler and more cost-effective method than the intricate process of creating lignocellulose-based hydrogels. This simplification helps convert abundant lignocellulosic materials into valuable products.

Graphical abstract: Lignocellulosic full-components hydrogelation using steam-exploded corn stover

Supplementary files

Article information

Article type
Paper
Submitted
01 Feb 2024
Accepted
17 Apr 2024
First published
18 Apr 2024

Green Chem., 2024,26, 6078-6088

Lignocellulosic full-components hydrogelation using steam-exploded corn stover

T. Pang, L. Wang and H. Chen, Green Chem., 2024, 26, 6078 DOI: 10.1039/D4GC00579A

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