Issue 9, 2024
From the journal:

Chemical Science

Borylated cyclobutanes via thermal [2 + 2]-cycloaddition†

Kateryna Prysiazhniuk,a   Oleksandr Polishchuk,a   Stanislav Shulha,a   Kyrylo Gudzikevych,a   Oleksandr P. Datsenko,a   Vladimir Kubyshkin ORCID logo a  and  Pavel K. Mykhailiuk ORCID logo *a  

* Corresponding authors

a Enamine Ltd, Winston Churchill St. 78, 02094 Kyiv, Ukraine
E-mail: Pavel.Mykhailiuk@gmail.com
Web: https://www.mykhailiukchem.org

Abstract

A one-step approach to borylated cyclobutanes from amides of carboxylic acids and vinyl boronates is elaborated. The reaction proceeds via the thermal [2 + 2]-cycloaddition of in situ-generated keteniminium salts.

Graphical abstract: Borylated cyclobutanes via thermal [2 + 2]-cycloaddition

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Article information

DOI
https://doi.org/10.1039/D3SC06600B
Article type
Edge Article
Submitted
08 Dec 2023
Accepted
17 Jan 2024
First published
25 Jan 2024
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY license

Chem. Sci., 2024,15, 3249-3254

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Borylated cyclobutanes via thermal [2 + 2]-cycloaddition

K. Prysiazhniuk, O. Polishchuk, S. Shulha, K. Gudzikevych, O. P. Datsenko, V. Kubyshkin and P. K. Mykhailiuk, Chem. Sci., 2024, 15, 3249 DOI: 10.1039/D3SC06600B

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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