Synthesis of biphenyl-based chiral amine catalysts from dibromopyrenes and their application in enamine catalysis

Yuki Uwaso; Naoki Yokoyama; Taichi Kano

doi:10.1039/D3OB01059G

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Synthesis of biphenyl-based chiral amine catalysts from dibromopyrenes and their application in enamine catalysis†

Yuki Uwaso,^a Naoki Yokoyama^b and Taichi Kano

*^b

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* Corresponding authors

^a Graduate School of Science, Kyoto University, Kyoto 606-8502, Japan

^b Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology, Tokyo 184-8588, Japan
E-mail: kano@go.tuat.ac.jp

Abstract

Novel axially chiral biphenyl-based amine catalysts have been designed and synthesized from dibromopyrenes. These chiral amines function as effective catalysts for asymmetric reactions through enamine intermediates.

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Article information

DOI: https://doi.org/10.1039/D3OB01059G
Article type: Communication
Submitted: 04 Jul 2023
Accepted: 26 Jul 2023
First published: 26 Jul 2023

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Org. Biomol. Chem., 2023,21, 6484-6487

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Synthesis of biphenyl-based chiral amine catalysts from dibromopyrenes and their application in enamine catalysis

Y. Uwaso, N. Yokoyama and T. Kano, Org. Biomol. Chem., 2023, 21, 6484 DOI: 10.1039/D3OB01059G

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Organic & Biomolecular Chemistry

Synthesis of biphenyl-based chiral amine catalysts from dibromopyrenes and their application in enamine catalysis†

Abstract

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Synthesis of biphenyl-based chiral amine catalysts from dibromopyrenes and their application in enamine catalysis

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