Issue 11, 2024
From the journal:

Chemical Communications

Stepwise construction of coordinative linkages and dynamic covalent linkages for a porous metal–organic framework†

Shuyin Peng,a   Yuqian Sun,a   Qingqing Li,a   Zhongwen Jiang,a   Yin Rao,a   Yichen Wua  and  Qiaowei Li ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Collaborative Innovation Center of Chemistry for Energy Materials, and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, P. R. China
E-mail: qwli@fudan.edu.cn

Abstract

A cyclic trinuclear complex is synthesized from AgI and 1H-pyrazole-4-carbaldehyde. Reticulation of the complex with 1,3,5-tris(4-aminophenyl)benzene through Schiff-base reaction affords a porous FDM-72 framework. Amine choice is systematically investigated as it may initiate metal reduction. This study proposes a new route and its amine selection criterion to synthesize Ag-based frameworks.

Graphical abstract: Stepwise construction of coordinative linkages and dynamic covalent linkages for a porous metal–organic framework

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Article information

DOI
https://doi.org/10.1039/D3CC05650C
Article type
Communication
Submitted
17 Nov 2023
Accepted
04 Jan 2024
First published
06 Jan 2024
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2024,60, 1488-1491

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Stepwise construction of coordinative linkages and dynamic covalent linkages for a porous metal–organic framework

S. Peng, Y. Sun, Q. Li, Z. Jiang, Y. Rao, Y. Wu and Q. Li, Chem. Commun., 2024, 60, 1488 DOI: 10.1039/D3CC05650C

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