Issue 4, 2023

A novel supramolecular Zn(ii)-metallogel: an efficient microelectronic semiconducting device application

Abstract

A unique strategy for the synthesis of a supramolecular metallogel employing zinc ions and adipic acid in DMF medium has been established at room temperature. Rheological analysis was used to investigate the mechanical characteristics of the supramolecular Zn(II)-metallogel. Field emission scanning electron microscopy and transmission electron microscopy were used to analyse the hexagonal shape morphological features of the Zn(II)-metallogel. Interestingly, the electrical conductivity is observed in the electronic device with Zn(II)-metallogel based metal–semiconductor (MS) junctions. All aspects of the metallogel's electrical properties were investigated. The electrical conductivity of the metallogel-based thin film device was 7.38 × 10−5 S m−1. The synthesised Zn(II)-metallogel based device was investigated for its semi-conductive properties, such as its Schottky barrier diode nature.

Graphical abstract: A novel supramolecular Zn(ii)-metallogel: an efficient microelectronic semiconducting device application

Supplementary files

Article information

Article type
Paper
Submitted
20 Nov 2022
Accepted
10 Jan 2023
First published
17 Jan 2023
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2023,13, 2561-2569

A novel supramolecular Zn(II)-metallogel: an efficient microelectronic semiconducting device application

K. Karmakar, A. Dey, S. Dhibar, R. Sahu, S. Bhattacharjee, P. Karmakar, P. Chatterjee, A. Mondal and B. Saha, RSC Adv., 2023, 13, 2561 DOI: 10.1039/D2RA07374A

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