Issue 4, 2023

Liquid-like and solid-like acetonitrile intercalated into graphite oxide as studied by the spin probe technique

Abstract

The molecular mobility of acetonitrile intercalated into the inter-plane space of graphite oxide was studied using the spin probe technique. It was revealed that two types of intercalated substance – liquid-like and solid-like – are simultaneously present in between the oxidized graphene planes, and their ratio depends on temperature. The micro-viscosity of liquid-like intercalated acetonitrile was found to be higher than that of bulk acetonitrile and depends on the amount of intercalated liquid.

Graphical abstract: Liquid-like and solid-like acetonitrile intercalated into graphite oxide as studied by the spin probe technique

Article information

Article type
Paper
Submitted
02 Aug 2022
Accepted
10 Nov 2022
First published
11 Nov 2022

Phys. Chem. Chem. Phys., 2023,25, 3136-3143

Liquid-like and solid-like acetonitrile intercalated into graphite oxide as studied by the spin probe technique

D. A. Astvatsaturov, A. I. Kokorin, M. Ya. Melnikov and N. A. Chumakova, Phys. Chem. Chem. Phys., 2023, 25, 3136 DOI: 10.1039/D2CP03548K

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