Issue 13, 2023

Ti-MOF single-crystals featuring an intracrystal macro–microporous hierarchy for catalytic oxidative desulfurization

Abstract

For the first time, we demonstrate a Ti-MOF (Ti-metal organic framework) single-crystal featuring an intracrystal macro–microporous hierarchy (Hier-NTU-9) by a vapor-assisted polymer-templated method. This Hier-NTU-9 possesses macropores (100–1000 nm) derived from polymer templates and enhanced transport ability of bulky molecules, exhibiting almost double the desulfurization activity compared to the conventional NTU-9.

Graphical abstract: Ti-MOF single-crystals featuring an intracrystal macro–microporous hierarchy for catalytic oxidative desulfurization

Supplementary files

Article information

Article type
Communication
Submitted
29 Nov 2022
Accepted
18 Jan 2023
First published
18 Jan 2023

Chem. Commun., 2023,59, 1801-1804

Ti-MOF single-crystals featuring an intracrystal macro–microporous hierarchy for catalytic oxidative desulfurization

S. Yu, Y. Xiao, Z. Liu, J. Lyu, Y. Wang, Z. Hu, Y. Li, M. Sun, L. Chen and B. Su, Chem. Commun., 2023, 59, 1801 DOI: 10.1039/D2CC06473A

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