Issue 71, 2022

Minor adjustments in the chemical structures of pyridine derivatives induced different co-assemblies by O–H⋯N hydrogen bonds

Abstract

The co-adsorption behaviours of aromatic carboxylic acids with various pyridine derivatives were investigated with scanning tunneling microscopy and density functional theory. Surprisingly, minor adjustments in the chemical structures of the pyridine derivatives, such as the relative position of the nitrogen atom or the lengths of the side chains on the backbone would evidently affect the intermolecular O–H⋯N hydrogen bonds and further form various co-adsorption structures.

Graphical abstract: Minor adjustments in the chemical structures of pyridine derivatives induced different co-assemblies by O–H⋯N hydrogen bonds

Supplementary files

Article information

Article type
Communication
Submitted
11 Jul 2022
Accepted
08 Aug 2022
First published
09 Aug 2022

Chem. Commun., 2022,58, 9914-9917

Minor adjustments in the chemical structures of pyridine derivatives induced different co-assemblies by O–H⋯N hydrogen bonds

P. Lei, W. Luo, B. Tu, X. Xiao, Q. Fang, C. Wang and Q. Zeng, Chem. Commun., 2022, 58, 9914 DOI: 10.1039/D2CC03859E

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