Solid polymer electrolytes (SPEs) for lithium metal batteries (LMBs) exhibit predominant safety over traditional carbonate-based organic liquid electrolytes. However, the low ionic conductivity of SPEs related to crystallinity at room temperature still hinders their practical application. The incorporation of nonflammable and ion-conductive ionic liquids (ILs) as plasticizer agents plays an active role in suppressing crystallinity. Herein, the relationship between the cations for ILs and the cycling performance of Li/LiFePO₄ batteries were investigated. EMIM⁺ demonstrates the best ability for reversible Li⁺ intercalation/deintercalation behavior over other cations due to its superior cationic solvation, highest ion conductivity and lowest viscosity. The Li/LiFePO₄ batteries based on the optimized EMIM⁺-encapsuled ionogel electrolyte could operate steadily over 120 cycles at 0.5C and room temperature. The results illustrate that the IL-plasticized hybrid electrolyte is a promising electrolyte candidate for room temperature solid state LMBs with high energy densities.