High nuclearity structurally – related Mn supertetrahedral T4 aggregates

Katerina Skordi; Antonis Anastassiades; Adeline D. Fournet; Rahul Kumar; Michael Schulze; Wolfgang Wernsdorfer; George Christou; Vassilios Nastopoulos; Spyros P. Perlepes; Constantina Papatriantafyllopoulou; Anastasios J. Tasiopoulos

doi:10.1039/D1CC01815A

High nuclearity structurally – related Mn supertetrahedral T4 aggregates†

Katerina Skordi,^a Antonis Anastassiades,^a Adeline D. Fournet,^b Rahul Kumar,^b Michael Schulze,

^c Wolfgang Wernsdorfer,

^c George Christou,

^b Vassilios Nastopoulos,

^d Spyros P. Perlepes,

^d Constantina Papatriantafyllopoulou

*^e and Anastasios J. Tasiopoulos

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of Cyprus, Nicosia 1678, Cyprus
E-mail: atasio@ucy.ac.cy

^b Department of Chemistry, University of Florida, Gainesville, Florida 32611-7200, USA

^c Institute of Quantum Materials and Technologies (IQMT), Hermann-von-Helmholtz-Platz 1, Eggenstein-Leopoldshafen, Germany

^d Department of Chemistry, University of Patras, Patras 26504, Greece

^e Synthesis and Solid-State Pharmaceutical Centre (SSPC), School of Chemistry, College of Science and Engineering, National University of Ireland Galway, University Road, Galway, Ireland
E-mail: constantina.papatriantafyllopo@nuigalway.ie

Abstract

The simultaneous employment of 1,3-propanediol and di-2-pyridyl ketone in Mn carboxylate chemistry has provided access to three new, structurally-related [Mn₂₄] and [Mn₂₃] clusters. They are based on nanosized supertetrahedal T4 Mn/O structural cores and exhibit slow relaxation of magnetization below 3.5 K.

Chemical Communications

High nuclearity structurally – related Mn supertetrahedral T4 aggregates†

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