Issue 94, 2020

Probing the peripheral role of amines in photo- and electrocatalytic H2 production by molecular cobalt complexes

Abstract

The incorporation of amine functionality in the periphery of a synthetic cobaloxime core induces excellent photo-(TON 180) and electrocatalytic H2 production (TOF 4330 sāˆ’1) in aqueous solution. The primary amine group displays a superior influence on the catalysis compared to a secondary amine group with an analogous cobaloxime template.

Graphical abstract: Probing the peripheral role of amines in photo- and electrocatalytic H2 production by molecular cobalt complexes

Supplementary files

Article information

Article type
Communication
Submitted
27 Aug 2020
Accepted
02 Nov 2020
First published
02 Nov 2020

Chem. Commun., 2020,56, 14841-14844

Probing the peripheral role of amines in photo- and electrocatalytic H2 production by molecular cobalt complexes

D. Dolui, A. Q. Mir and A. Dutta, Chem. Commun., 2020, 56, 14841 DOI: 10.1039/D0CC05786J

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