Issue 50, 2020
From the journal:

Chemical Communications

Storage and release of two electrons from an electron-rich carbon–carbon bond: boron mediated reversible coupling of DMAP and 9-azajulolidine†

Yunshu Cui,‡a   Libo Xiang,‡a   Junyi Wang,a   Chunlei Li,a   Wei Haoa  and  Qing Ye ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Southern University of Science and Technology, 518055 Shenzhen, P. R. China
E-mail: yeq3@sustech.edu.cn

Abstract

This manuscript describes the preparation of [{(dpp-bian)BBr}Li(DME)3] (2, dpp-bian = 1,2-bis[(2,6-diisopropylphenyl) imino]acenaphthene) and [{(dpp-bian)BL}+Br−] (5, L = DMAP; 6, L = 9-azajulolidine). The 4,4-coupling of DMAP and 2,2-coupling of 9-azajulolidine can be achieved either by the reaction of 2 with L, or by one-electron reduction of borenium cations 5 and 6. Oxidation of 3 and 4 leads to C–C cleavage and regeneration of 5 and 6. All new compounds have been structurally characterized.

Graphical abstract: Storage and release of two electrons from an electron-rich carbon–carbon bond: boron mediated reversible coupling of DMAP and 9-azajulolidine

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D0CC01575J
Article type
Communication
Submitted
28 Feb 2020
Accepted
12 May 2020
First published
12 May 2020

Chem. Commun., 2020,56, 6794-6797

Permissions

Request permissions

Storage and release of two electrons from an electron-rich carbon–carbon bond: boron mediated reversible coupling of DMAP and 9-azajulolidine

Y. Cui, L. Xiang, J. Wang, C. Li, W. Hao and Q. Ye, Chem. Commun., 2020, 56, 6794 DOI: 10.1039/D0CC01575J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements