A hexaarm hexachloropolystyrene star polymer 1 (![[M with combining macron]](https://www.rsc.org/images/entities/char_004d_0304.gif)
n= 18 000 g mol–1) is functionalized by reaction with Me3SiN3 to give the hexaazido star polymer 2; reduction of 2 by PPh3/H2O leads to the hexaamine star polymer 3, and reaction of 2 with a two-fold excess of C60 gives the hexafullerence star polymer 4, characterized by size-exclusion chromatography, NMR, thermal-gravimetry analysis and CV.
E. Cloutet, Y. Gnanou, J. Fillaut and D. Astruc, Chem. Commun., 1996, 1565 DOI: 10.1039/CC9960001565
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