Introducing the Tishchenko reaction into sustainable polymer chemistry

Tianhua Ren; Qin Chen; Changbo Zhao; Qiang Zheng; Haibo Xie; Michael North

doi:10.1039/C9GC03926K

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Introducing the Tishchenko reaction into sustainable polymer chemistry†

Tianhua Ren,^a Qin Chen,*^a Changbo Zhao,^a Qiang Zheng,^b Haibo Xie

*^a and Michael North

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* Corresponding authors

^a Department of Polymeric Materials & Engineering, College of Materials & Metallurgy, Guizhou University, West Campus, Huaxi District, Guiyang 550025, P. R. China
E-mail: qchen6@gzu.edu.cn, hbxie@gzu.educn

^b Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China

^c Green Chemistry Centre of Excellence, Department of Chemistry, University of York, YO10 5DD, Heslington, York, UK

Abstract

Taking advantage of the structural characteristics of lignin-derived phenolic compounds, a combination of the Williamson and Tishchenko reactions produced a series of new α,ω-diene functionalized carboxylic ester monomers from both petrochemical and renewable resources, which were applicable in subsequent thiol–ene click and acyclic diene metathesis (ADMET) polymerizations, providing a series of poly(thioether esters) and unsaturated aromatic–aliphatic polyesters with high molecular weights.

This article is part of the themed collection: 2020 Green Chemistry Hot Articles

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Article information

DOI: https://doi.org/10.1039/C9GC03926K
Article type: Communication
Submitted: 14 Nov 2019
Accepted: 23 Dec 2019
First published: 23 Dec 2019

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Green Chem., 2020,22, 1542-1547

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Introducing the Tishchenko reaction into sustainable polymer chemistry

T. Ren, Q. Chen, C. Zhao, Q. Zheng, H. Xie and M. North, Green Chem., 2020, 22, 1542 DOI: 10.1039/C9GC03926K

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Introducing the Tishchenko reaction into sustainable polymer chemistry†

Abstract

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Introducing the Tishchenko reaction into sustainable polymer chemistry

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