Issue 43, 2018, Issue in Progress

A systematic study of the co-solvent effect for an all-organic redox flow battery

Abstract

Benzophenone and 1,4-di-tert-butyl-2,5-dimethoxybenzene are used as the anode and cathode active species respectively in an all-organic redox-flow battery. A number of organics as the co-solvents are applied in the electrolyte to improve the electrochemical performance of it. For all kinds of the mixed solvents, a lower content of acetonitrile leads to a higher solubility to 1,4-di-tert-butyl-2,5-dimethoxybenzene and a lower conductivity. The results of cyclic voltammetry tests demonstrate that the electrode reactions are controlled by diffusion. With the decrease of the content of acetonitrile, the dynamic viscosity of the electrolyte increases, which generally leads to the decrease of the diffusion coefficients of the active species.

Graphical abstract: A systematic study of the co-solvent effect for an all-organic redox flow battery

Article information

Article type
Paper
Submitted
22 Mar 2018
Accepted
29 Jun 2018
First published
06 Jul 2018
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2018,8, 24422-24427

A systematic study of the co-solvent effect for an all-organic redox flow battery

X. Wang, X. Xing, Y. Huo, Y. Zhao and Y. Li, RSC Adv., 2018, 8, 24422 DOI: 10.1039/C8RA02513D

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