Issue 16, 2019
From the journal:

Chemical Communications

Solvent-assisted synthesis of a shape-persistent chiral polyaza gigantocycle characterized by a very large internal cavity and extraordinarily high amplitude of the ECD exciton couplet†

Mikołaj Zgorzelak, ORCID logo *a   Jakub Grajewski, ORCID logo a   Jacek Gawroński ORCID logo a  and  Marcin Kwit ORCID logo *ab  

* Corresponding authors

a Department of Chemistry, Adam Mickiewicz University, Umultowska 89B, 61 614 Poznań, Poland
E-mail: mikolaj.zgorzelak@amu.edu.pl, marcin.kwit@amu.edu.pl

b Centre for Advanced Technologies, Adam Mickiewicz University, Umultowska 89C, 61 614 Poznań, Poland

Abstract

A giant, chiral square-shaped octaimine macrocycle has been obtained in a controlled manner from readily available and inexpensive substrates: 9,10-diphenylanthracene-based dialdehyde and trans-1,2-diaminocyclohexane. Reduction of the polyimine led to a chiral octaamine characterized by a very large internal hydrophobic cavity.

Graphical abstract: Solvent-assisted synthesis of a shape-persistent chiral polyaza gigantocycle characterized by a very large internal cavity and extraordinarily high amplitude of the ECD exciton couplet

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Article information

DOI
https://doi.org/10.1039/C8CC10184A
Article type
Communication
Submitted
24 Dec 2018
Accepted
25 Jan 2019
First published
25 Jan 2019

Chem. Commun., 2019,55, 2301-2304

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Solvent-assisted synthesis of a shape-persistent chiral polyaza gigantocycle characterized by a very large internal cavity and extraordinarily high amplitude of the ECD exciton couplet

M. Zgorzelak, J. Grajewski, J. Gawroński and M. Kwit, Chem. Commun., 2019, 55, 2301 DOI: 10.1039/C8CC10184A

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