Issue 33, 2018
From the journal:

Chemical Communications

A high-valent di-μ-oxo dimanganese complex covalently anchored in a metal–organic framework as a highly efficient and recoverable water oxidation catalyst†

Lina Zhang,a   Junying Chen, ORCID logo *a   Ting Fan,a   Kui Shen, ORCID logo a   Miao Jianga  and  Yingwei Li ORCID logo *a  

* Corresponding authors

a State Key Laboratory of Pulp and Paper Engineering, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China
E-mail: chenjunying2010@sina.com, liyw@scut.edu.cn

Abstract

A biomimetic di-μ-oxo dimanganese complex bearing two triazole-binding tridentate ligands is successfully anchored inside a metal–organic framework (MOF) through a covalent-functionalization-assisted coordination strategy, exhibiting high activity and reliable durability in the chemical water oxidation reaction.

Graphical abstract: A high-valent di-μ-oxo dimanganese complex covalently anchored in a metal–organic framework as a highly efficient and recoverable water oxidation catalyst

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Article information

DOI
https://doi.org/10.1039/C8CC00258D
Article type
Communication
Submitted
11 Jan 2018
Accepted
29 Mar 2018
First published
29 Mar 2018

Chem. Commun., 2018,54, 4188-4191

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A high-valent di-μ-oxo dimanganese complex covalently anchored in a metal–organic framework as a highly efficient and recoverable water oxidation catalyst

L. Zhang, J. Chen, T. Fan, K. Shen, M. Jiang and Y. Li, Chem. Commun., 2018, 54, 4188 DOI: 10.1039/C8CC00258D

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