Issue 66, 2016, Issue in Progress
From the journal:

RSC Advances

Catalytic enantioselective oxa-hetero-Diels–Alder reactions of enones with aryl trifluoromethyl ketones†

Dongxin Zhanga  and  Fujie Tanaka*a  

* Corresponding authors

a Chemistry and Chemical Bioengineering Unit, Okinawa Institute of Science and Technology Graduate University, 1919-1 Tancha, Onna, Okinawa 904-0495, Japan
E-mail: ftanaka@oist.jp

Abstract

The development of oxa-hetero-Diels–Alder reactions of enones with aryl trifluoromethyl ketones to afford tetrahydropyranones bearing trifluoromethyl-substituted tetrasubstituted carbon centers is reported. The reactions were catalyzed by an amine-based catalyst system and afforded the products with er values up to 97 : 3.

Graphical abstract: Catalytic enantioselective oxa-hetero-Diels–Alder reactions of enones with aryl trifluoromethyl ketones

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Article information

DOI
https://doi.org/10.1039/C6RA13859D
Article type
Communication
Submitted
28 May 2016
Accepted
18 Jun 2016
First published
21 Jun 2016
This article is Open Access
Creative Commons BY license

RSC Adv., 2016,6, 61454-61457

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Catalytic enantioselective oxa-hetero-Diels–Alder reactions of enones with aryl trifluoromethyl ketones

D. Zhang and F. Tanaka, RSC Adv., 2016, 6, 61454 DOI: 10.1039/C6RA13859D

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