Issue 14, 2016
From the journal:

Catalysis Science & Technology

Non-directed aromatic C–H amination: catalytic and mechanistic studies enabled by Pd catalyst and reagent design†

H. M. D. Bandara,‡a   D. Jin,‡a   M. A. Mantell,a   K. D. Field,§a   A. Wang,a   R. P. Narayanan,a   N. A. Deskins§b  and  M. H. Emmert*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, Worcester Polytechnic Institute, 100 Institute Road, Worcester, MA, USA
E-mail: mhemmert@wpi.edu

b Department of Chemical Engineering, Worcester Polytechnic Institute, 100 Institute Road, Worcester, MA, USA

Abstract

This manuscript describes the systematic development of pyridine-type ligands, which promote the Pd catalyzed, non-directed amination of benzene in combination with novel, hydroxylamine-based electrophilic amination reagents. DFT calculations and mechanistic experiments provide insights into the factors influencing the arene C–H amination protocol.

Graphical abstract: Non-directed aromatic C–H amination: catalytic and mechanistic studies enabled by Pd catalyst and reagent design

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Article information

DOI
https://doi.org/10.1039/C6CY00457A
Article type
Paper
Submitted
29 Feb 2016
Accepted
23 Mar 2016
First published
24 Mar 2016

Catal. Sci. Technol., 2016,6, 5304-5310

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Non-directed aromatic C–H amination: catalytic and mechanistic studies enabled by Pd catalyst and reagent design

H. M. D. Bandara, D. Jin, M. A. Mantell, K. D. Field, A. Wang, R. P. Narayanan, N. A. Deskins and M. H. Emmert, Catal. Sci. Technol., 2016, 6, 5304 DOI: 10.1039/C6CY00457A

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