Issue 75, 2015
From the journal:

RSC Advances

Light-mediated cascade transformation of activated alkenes: BiOBr nanosheets as efficient photocatalysts for the synthesis of α-aryl-β-trifluoromethyl amides†

Cuibo Liua  and  Bin Zhang*a  

* Corresponding authors

a Department of Chemistry, School of Science, Tianjin University, and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072, P. R. China
E-mail: bzhang@tju.edu.cn

Abstract

A facile light-induced, BiOBr nanosheet promoted one-pot tandem transformation of activated alkenes is presented. A wide variety of acyclic α-aryl-β-trifluoromethyl amides are synthesized via the consecutive trifluoromethylation/aryl migration/desulfonylation and N–H bond formation process.

Graphical abstract: Light-mediated cascade transformation of activated alkenes: BiOBr nanosheets as efficient photocatalysts for the synthesis of α-aryl-β-trifluoromethyl amides

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Article information

DOI
https://doi.org/10.1039/C5RA08996D
Article type
Communication
Submitted
14 May 2015
Accepted
07 Jul 2015
First published
07 Jul 2015

RSC Adv., 2015,5, 61199-61203

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Light-mediated cascade transformation of activated alkenes: BiOBr nanosheets as efficient photocatalysts for the synthesis of α-aryl-β-trifluoromethyl amides

C. Liu and B. Zhang, RSC Adv., 2015, 5, 61199 DOI: 10.1039/C5RA08996D

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