Exceptional thermal stability of undoped anatase TiO2 photocatalysts prepared by a solvent-exchange method

Igor Krivtsov; Marina Ilkaeva; Viacheslav Avdin; Zakariae Amghouz; Sergei A. Khainakov; José R. García; Eva Díaz; Salvador Ordóñez

doi:10.1039/C5RA01114K

Exceptional thermal stability of undoped anatase TiO₂ photocatalysts prepared by a solvent-exchange method†

Igor Krivtsov,*^ab Marina Ilkaeva,^ac Viacheslav Avdin,^bc Zakariae Amghouz,^d Sergei A. Khainakov,^d José R. García,^a Eva Díaz^e and Salvador Ordóñez^e

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* Corresponding authors

^a Department of Organic and Inorganic Chemistry, University of Oviedo-CINN, 33006 Oviedo, Spain
E-mail: uo247495@uniovi.es, zapasoul@gmail.com
Tel: +34 684348116

^b Nanotechnology Education and Research Center, South Ural State University, Chelyabinsk, Russia

^c Department of Chemistry, South Ural State University, 454080 Chelyabinsk, Russia

^d Servicios Científico-Técnicos, Universidad de Oviedo, 33006 Oviedo, Spain

^e Department of Chemical and Environmental Engineering, University of Oviedo, 33006 Oviedo, Spain

Abstract

A new solvent-exchange technique to prepare anatase nanoparticles with exceptional thermal stability and photocatalytic activity is described here. The process of preparation is accomplished by using organic solvents to precipitate hydrous titania particles from a basic aqueous medium containing a titanium peroxo complex. Undoped titanium dioxide formed via a solvent exchange method has unprecedented thermal stability against transformation to the rutile phase, as opposed to TiO₂ prepared by the common method of the gelation of an aqueous titanium peroxo complex. On the basis of X-ray thermodiffraction experiments, it has been established that the thermal treatment at 1000 °C of the titania prepared by ethanol precipitation contains 100% pure anatase phase. The stabilization of anatase is induced by the high defectiveness of the TiO₂ nanostructure, which is evidenced from band-gap energy estimation, PXRD and HRTEM studies. The prepared TiO₂ nanoparticles show an outstanding photocatalytic activity comparable to the commercial Aeroxide P25 photocatalyst in the UV-assisted decomposition of methylene blue.

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Article information

DOI: https://doi.org/10.1039/C5RA01114K
Article type: Paper
Submitted: 19 Jan 2015
Accepted: 16 Apr 2015
First published: 16 Apr 2015

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RSC Adv., 2015,5, 36634-36641

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Exceptional thermal stability of undoped anatase TiO₂ photocatalysts prepared by a solvent-exchange method

I. Krivtsov, M. Ilkaeva, V. Avdin, Z. Amghouz, S. A. Khainakov, J. R. García, E. Díaz and S. Ordóñez, RSC Adv., 2015, 5, 36634 DOI: 10.1039/C5RA01114K

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