Issue 26, 2015

Efficient synthesis and stabilization of poly(propylene carbonate) from delicately designed bifunctional aluminum porphyrin complexes

Abstract

Bifunctional aluminum porphyrin complexes were designed to synthesize poly(propylene carbonate) (PPC) by copolymerization of propylene oxide and carbon dioxide. The catalytic performance is adjustable via delicate control of the electronic environment of the central Al by the number of methoxy groups in the ligand framework as well as the length of the alkyl chain in the quaternary ammonium cation. The optimal catalyst having six methoxy groups in the ligand framework, two trihexylammonium cations linked to benzene via a six-methylene spacer, and NO3 as the axial ligand and quaternary ammonium anions exhibited a TOF of 1320 h−1 at 80 °C and 3 MPa, and a PPC selectivity of 93%, and the TOF even reached 2824 h−1 at 90 °C and 3 MPa, while the PPC selectivity remained at 89%, the highest recorded in aluminum porphyrin complexes to date. In another concern, even though the bifunctional aluminum porphyrin complex has a soil-compostable feature and can be left in PPC without separation, the depolymerization was very rapid even at 25 °C under an ambient atmosphere, and over a 50% decrease in number average molecular weight was observed in 8 days, which could be stabilized by treatment with aqueous HCl solution.

Graphical abstract: Efficient synthesis and stabilization of poly(propylene carbonate) from delicately designed bifunctional aluminum porphyrin complexes

Supplementary files

Article information

Article type
Paper
Submitted
07 Mar 2015
Accepted
26 Apr 2015
First published
28 Apr 2015

Polym. Chem., 2015,6, 4719-4724

Author version available

Efficient synthesis and stabilization of poly(propylene carbonate) from delicately designed bifunctional aluminum porphyrin complexes

X. Sheng, W. Wu, Y. Qin, X. Wang and F. Wang, Polym. Chem., 2015, 6, 4719 DOI: 10.1039/C5PY00335K

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