Issue 33, 2015
From the journal:

Organic & Biomolecular Chemistry

Nazarov cyclization of dienylaziridines: synthesis of cyclopentadienyl/hydrinedienyl/indenyl glycines†

Gangarajula Sudhakar,*ab   Karla Janardhan Reddyab  and  Jagadesh Babu Nanuboluc  

* Corresponding authors

a Division of CPC (Organic Chemistry-II), CSIR-Indian Institute of Chemical Technology, Tarnaka, Hyderabad-500007, India
E-mail: gsudhakar@iict.res.in
Tel: +91-40-27191435

b Academy of Scientific and Innovative Research, New Delhi, India

c Center for X-Ray Crystallography, CSIR-IICT, India

Abstract

Cyclopentadienyl, hydrinedienyl, and indenyl glycines were synthesized using dienylaziridines as Nazarov cyclization precursors for the first time. Several substrates were synthesized to demonstrate the compatibility of this reaction. Asymmetric synthesis of these amino acids was also developed to show the additional scope of this method.

Graphical abstract: Nazarov cyclization of dienylaziridines: synthesis of cyclopentadienyl/hydrinedienyl/indenyl glycines

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C5OB01219H
Article type
Paper
Submitted
15 Jun 2015
Accepted
15 Jul 2015
First published
15 Jul 2015

Org. Biomol. Chem., 2015,13, 8875-8885

Permissions

Request permissions

Nazarov cyclization of dienylaziridines: synthesis of cyclopentadienyl/hydrinedienyl/indenyl glycines

G. Sudhakar, K. J. Reddy and J. B. Nanubolu, Org. Biomol. Chem., 2015, 13, 8875 DOI: 10.1039/C5OB01219H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements