Issue 82, 2015
From the journal:

Chemical Communications

Enhanced luminescence stability with a Tb–spin crossover nanocomposite for spin state monitoring†

I. Suleimanov,ab   O. Kraieva,a   G. Molnár,a   L. Salmon*a  and  A. Bousseksou*a  

* Corresponding authors

a Laboratoire de Chimie de Coordination, CNRS & Université de Toulouse (INPT, UPS), Toulouse, France
E-mail: lionel.salmon@lcc-toulouse.fr, azzedine.bousseksou@lcc-toulouse.fr

b Department of Chemistry, National Taras Shevchenko University, 62a Volodymyrska Street, 01601 Kyiv, Ukraine

Abstract

[Fe(Htrz)2(trz)]BF4@SiO2 nanorods were synthesized using a reverse emulsion technique and a Tb3+ complex was chemically bound to the silica surface. This Tb–spin crossover nanocomposite demonstrates high luminescence stability under continuous thermal cycling. A reabsorption mechanism is determined to be responsible for the luminescence intensity variation during the spin state switching of the iron complex.

Graphical abstract: Enhanced luminescence stability with a Tb–spin crossover nanocomposite for spin state monitoring

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Article information

DOI
https://doi.org/10.1039/C5CC06426K
Article type
Communication
Submitted
31 Jul 2015
Accepted
25 Aug 2015
First published
25 Aug 2015

Chem. Commun., 2015,51, 15098-15101

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Enhanced luminescence stability with a Tb–spin crossover nanocomposite for spin state monitoring

I. Suleimanov, O. Kraieva, G. Molnár, L. Salmon and A. Bousseksou, Chem. Commun., 2015, 51, 15098 DOI: 10.1039/C5CC06426K

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