Issue 4, 2015

Sandwich-like Cr2O3–graphite intercalation composites as high-stability anode materials for lithium-ion batteries

Abstract

Novel sandwich-like Cr2O3–graphite intercalation composites (Cr2O3–GICs) were synthesized via an intercalation–transformation method. Cr2O3 nanoparticles (NPs) are intercalated between the adjacent carbon layers of graphite and tightly immobilized. The Cr2O3–GICs show promising performance as anode materials for LIBs with a reversible capacity of about 480 mA h g−1 and a relatively low lithium insertion potential. More importantly, the Cr2O3–GICs demonstrate an extremely promising stable cycling performance with over 100% capacity retention after 1000 cycles. Furthermore, the intercalation–transformation method also provides another fabrication method of graphene-based assembled materials.

Graphical abstract: Sandwich-like Cr2O3–graphite intercalation composites as high-stability anode materials for lithium-ion batteries

Supplementary files

Article information

Article type
Paper
Submitted
25 Sep 2014
Accepted
06 Nov 2014
First published
06 Nov 2014

J. Mater. Chem. A, 2015,3, 1703-1708

Author version available

Sandwich-like Cr2O3–graphite intercalation composites as high-stability anode materials for lithium-ion batteries

F. Wang, W. Li, M. Hou, C. Li, Y. Wang and Y. Xia, J. Mater. Chem. A, 2015, 3, 1703 DOI: 10.1039/C4TA05072J

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