Issue 11, 2014
From the journal:

New Journal of Chemistry

Microporous metal–organic layer built from pentanuclear tetrahedral units: gas sorption and magnetism†

Yan-Xi Tan,ab   Ying Zhang,*a   Yan-Ping He*b  and  Yan-Jun Zheng*a  

* Corresponding authors

a State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing, No. 18 FuXue Road, ChangPing District, Beijing 102249, P. R. China
E-mail: tanyanxi2006@163.com, yingzh1977@163.com

b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China

Abstract

Presented herein is a porous layer motif 1 built from pentanuclear tetrahedral Ni-clusters with accessible metal centers. Activated 1 exhibits a high selectivity of 19.8 at 273 K and 1 bar for the separation of CO2 over CH4. Magnetic measurement shows the overall antiferromagnetic coupling between Ni(II) ions for 1.

Graphical abstract: Microporous metal–organic layer built from pentanuclear tetrahedral units: gas sorption and magnetism

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Article information

DOI
https://doi.org/10.1039/C4NJ00517A
Article type
Letter
Submitted
04 Apr 2014
Accepted
03 Sep 2014
First published
05 Sep 2014

New J. Chem., 2014,38, 5272-5275

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Microporous metal–organic layer built from pentanuclear tetrahedral units: gas sorption and magnetism

Y. Tan, Y. Zhang, Y. He and Y. Zheng, New J. Chem., 2014, 38, 5272 DOI: 10.1039/C4NJ00517A

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