Issue 29, 2014

Fabrication and performance studies of a cable-type flexible asymmetric supercapacitor

Abstract

In the present work a novel cable-type asymmetric supercapacitor was fabricated using plate-like β-Ni(OH)2 as the positive and activated carbon as the negative electrode, with polyvinyl alcohol–KOH (PVA–KOH) as the gel polymer electrolyte. The β-Ni(OH)2 plates were prepared by a reflux method and the activated carbon was derived from Tamarindus indica fruit shell by chemical activation. The working voltage of the fabricated cable-type asymmetric supercapacitor (ASC) was 1.4 V, and it achieved per-unit-length and gravimetric capacitances of 40.7 mF cm−1 and 37.5 F g−1 respectively at 2 mA. Besides, the fabricated ASC delivered a maximum per-unit-length (gravimetric) energy density of 10.7 μW h cm−1 (9.8 W h kg−1) at a power density of 169 μW cm−1 (154 W kg−1). In addition, it exhibited a better capacitance retention, of 88% over 1000 cylces and 76% over 2000 cycles.

Graphical abstract: Fabrication and performance studies of a cable-type flexible asymmetric supercapacitor

Supplementary files

Article information

Article type
Paper
Submitted
05 Mar 2014
Accepted
06 May 2014
First published
24 Jun 2014

Phys. Chem. Chem. Phys., 2014,16, 15692-15698

Fabrication and performance studies of a cable-type flexible asymmetric supercapacitor

S. T. Senthilkumar and R. Kalai Selvan, Phys. Chem. Chem. Phys., 2014, 16, 15692 DOI: 10.1039/C4CP00955J

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