Issue 82, 2014
From the journal:

Chemical Communications

On the coordination chemistry of phosphinecarboxamide: assessing ligand basicity†

M. B. Geeson,a   A. R. Jupp,a   J. E. McGradya  and  J. M. Goicoechea*a  

* Corresponding authors

a Department of Chemistry, University of Oxford, Inorganic Chemistry Laboratory, South Parks Road, Oxford, UK
E-mail: jose.goicoechea@chem.ox.ac.uk

Abstract

We describe the coordination chemistry of the primary phosphine PH2C(O)NH2 (phosphinecarboxamide) towards group 6 transition-metals. Experimental and theoretical studies reveal that this novel species has comparable electronic properties to PH3.

Graphical abstract: On the coordination chemistry of phosphinecarboxamide: assessing ligand basicity

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Article information

DOI
https://doi.org/10.1039/C4CC06094F
Article type
Communication
Submitted
04 Aug 2014
Accepted
26 Aug 2014
First published
27 Aug 2014

Chem. Commun., 2014,50, 12281-12284

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On the coordination chemistry of phosphinecarboxamide: assessing ligand basicity

M. B. Geeson, A. R. Jupp, J. E. McGrady and J. M. Goicoechea, Chem. Commun., 2014, 50, 12281 DOI: 10.1039/C4CC06094F

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