Issue 75, 2014
From the journal:

Chemical Communications

Cu-Catalyzed Suzuki–Miyaura reactions of primary and secondary benzyl halides with arylboronates†

Yan-Yan Sun,a   Jun Yi,a   Xi Lu,a   Zhen-Qi Zhang,a   Bin Xiaoa  and  Yao Fu*a  

* Corresponding authors

a Anhui Province Key Laboratory of Biomass Clean Energy Department of Chemistry, University of Science and Technology of China, Hefei 230026, P. R. China
E-mail: fuyao@ustc.edu.cn

Abstract

A copper-catalyzed Suzuki–Miyaura coupling of benzyl halides with arylboronates is described. Varieties of primary benzyl halides as well as more challenging secondary benzyl halides with β hydrogens or steric hindrance could be successfully converted into the corresponding products. Thus it provides access to diarylmethanes, diarylethanes and triarylmethanes.

Graphical abstract: Cu-Catalyzed Suzuki–Miyaura reactions of primary and secondary benzyl halides with arylboronates

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C4CC05376A
Article type
Communication
Submitted
12 Jul 2014
Accepted
29 Jul 2014
First published
31 Jul 2014

Chem. Commun., 2014,50, 11060-11062

Author version available

Download author version (PDF)

Permissions

Request permissions

Cu-Catalyzed Suzuki–Miyaura reactions of primary and secondary benzyl halides with arylboronates

Y. Sun, J. Yi, X. Lu, Z. Zhang, B. Xiao and Y. Fu, Chem. Commun., 2014, 50, 11060 DOI: 10.1039/C4CC05376A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements