Issue 76, 2014
From the journal:

Chemical Communications

Synthesis of 1,3,5,7-tetrakis(4-cyanatophenyl)adamantane and its microporous polycyanurate network for adsorption of organic vapors, hydrogen and carbon dioxide†

Changjiang Shen,a   Hao Yua  and  Zhonggang Wang*a  

* Corresponding authors

a State Key Laboratory of Fine Chemicals, Department of Polymer Science and Materials, School of Chemical Engineering, Dalian University of Technology, Dalian, China
E-mail: zgwang@dlut.edu.cn

Abstract

This report presents the synthesis of a tetraphenyladamantane-based microporous polycyanurate network with a BET surface area of 843 m2 g−1 and a pore size of 7.8 Å. It uptakes 98.0 wt% benzene (298 K, P/P0 = 0.9), 1.49 wt% H2 (77 K/1 bar) and 12.8 wt% CO2 (273 K/1 bar) with CO2/N2 selectivity of up to 112.

Graphical abstract: Synthesis of 1,3,5,7-tetrakis(4-cyanatophenyl)adamantane and its microporous polycyanurate network for adsorption of organic vapors, hydrogen and carbon dioxide

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Article information

DOI
https://doi.org/10.1039/C4CC05021E
Article type
Communication
Submitted
01 Jul 2014
Accepted
27 Jul 2014
First published
28 Jul 2014

Chem. Commun., 2014,50, 11238-11241

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Synthesis of 1,3,5,7-tetrakis(4-cyanatophenyl)adamantane and its microporous polycyanurate network for adsorption of organic vapors, hydrogen and carbon dioxide

C. Shen, H. Yu and Z. Wang, Chem. Commun., 2014, 50, 11238 DOI: 10.1039/C4CC05021E

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