Issue 17, 2013
From the journal:

Organic & Biomolecular Chemistry

Rhodium(iii)-catalyzed oxidative olefination of N-allyl sulfonamides†

Shui Hu,ab   Dongqi Wang,b   Jiexiang Liua  and  Xingwei Li*b  

* Corresponding authors

a School of Chemical Engineering, Hebei University of Technology, Tianjin 300130, PR China

b Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, PR China
E-mail: xwli@dicp.ac.cn

Abstract

Rhodium(III)-catalyzed oxidative couplings between N-sulfonyl allylamines and activated olefins have been achieved. Only olefination occurred for acrylates, and the butadiene product can be further cyclized under palladium-catalyzed aerobic conditions. The coupling with N,N-dimethylacrylamide followed a cyclization pathway.

Graphical abstract: Rhodium(iii)-catalyzed oxidative olefination of N-allyl sulfonamides

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Article information

DOI
https://doi.org/10.1039/C3OB40272J
Article type
Communication
Submitted
06 Feb 2013
Accepted
09 Mar 2013
First published
12 Mar 2013

Org. Biomol. Chem., 2013,11, 2761-2765

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Rhodium(III)-catalyzed oxidative olefination of N-allyl sulfonamides

S. Hu, D. Wang, J. Liu and X. Li, Org. Biomol. Chem., 2013, 11, 2761 DOI: 10.1039/C3OB40272J

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