SCHEDULED MAINTENANCE
The selective catalytic hydrosilylation of functional groups is becoming an interesting tool for organic synthesis. In the present study, fluoride-catalyzed hydrosilylations of aromatic nitriles have been examined in detail. Using catalytic amounts of inexpensive tetra-n-butylammonium fluoride (TBAF) various aromatic nitriles are reduced in good yields under mild conditions.
C. Bornschein, S. Werkmeister, K. Junge and M. Beller, New J. Chem., 2013, 37, 2061 DOI: 10.1039/C3NJ00171G
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