Issue 9, 2014

Top-seeded solution growth of SrTiO3 crystals and phase diagram studies in the SrO–TiO2 system

Abstract

The TiO2 rich part of the (1 − x)SrO + xTiO2 phase diagram (0.5 ≤ x ≤ 1.0) was redetermined and the eutectic point between SrTiO3 and TiO2 was found at xeut = 0.7700 ± 0.0001; Teut = 1449 ± 3 °C. From TiO2 rich melt solutions, x = 0.75, centimeter-sized single crystals could be grown. The best crystals with an etch pit density of <2 × 104 cm−2 were obtained for growth directions 〈110〉 and 〈100〉. AFM investigation of the interface reveals layer-by-layer growth.

Graphical abstract: Top-seeded solution growth of SrTiO3 crystals and phase diagram studies in the SrO–TiO2 system

Article information

Article type
Paper
Submitted
09 Oct 2013
Accepted
09 Dec 2013
First published
10 Dec 2013

CrystEngComm, 2014,16, 1735-1740

Top-seeded solution growth of SrTiO3 crystals and phase diagram studies in the SrO–TiO2 system

C. Guguschev, D. Klimm, F. Langhans, Z. Galazka, D. Kok, U. Juda and R. Uecker, CrystEngComm, 2014, 16, 1735 DOI: 10.1039/C3CE42037J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements