Issue 86, 2013
From the journal:

Chemical Communications

Controlled homopolymerization of multi-vinyl monomers: dendritic polymers synthesized via an optimized ATRA reaction†

Yu Zheng,‡a   Tianyu Zhao,‡a   Ben Newland,a   Julien Polyb  and  Wenxin Wang*a  

* Corresponding authors

a Network of Excellence for Functional Biomaterials, National University of Ireland, Galway, Ireland
E-mail: wenxin.wang@nuigalway.ie

b Institut de Science des Matériaux de Mulhouse (IS2M) – UMR 7361 – CNRS/UHA, 15 rue Jean Starcky, 68057 Mulhouse, France

Abstract

In this study, we have managed to find the optimal ATRA system that can obtain the highest mono-adduct yields with the purpose of minimizing the chain growth of divinyl monomers. The most highly hyperbranched polymers have been synthesized by the homopolymerization of multi-vinyl monomers via ATRA reaction.

Graphical abstract: Controlled homopolymerization of multi-vinyl monomers: dendritic polymers synthesized via an optimized ATRA reaction

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Article information

DOI
https://doi.org/10.1039/C3CC44898C
Article type
Communication
Submitted
30 Jun 2013
Accepted
23 Aug 2013
First published
23 Aug 2013

Chem. Commun., 2013,49, 10124-10126

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Controlled homopolymerization of multi-vinyl monomers: dendritic polymers synthesized via an optimized ATRA reaction

Y. Zheng, T. Zhao, B. Newland, J. Poly and W. Wang, Chem. Commun., 2013, 49, 10124 DOI: 10.1039/C3CC44898C

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