Issue 52, 2013
From the journal:

Chemical Communications

Efficient ruthenium-catalysed S–S, S–Si and S–B bond forming reactions†

José A. Fernández-Salas,a   Simone Manzinia  and  Steven P. Nolan*a  

* Corresponding authors

a EaStCHEM School of Chemistry, University of St Andrews, St Andrews, UK
E-mail: snolan@st-andrews.ac.uk

Abstract

[RuCl(PPh3)2(3-phenylindenyl)] (1) has been shown to be an efficient catalyst in thiol dehydrogenative coupling to give disulfides. Moreover, an efficient procedure for the preparation of silylthioethers and thioboranes is presented. Complex 1 demonstrated a great ability to catalyse the coupling of thiols with silanes and boranes under mild conditions with excellent results (turnover number up to 200).

Graphical abstract: Efficient ruthenium-catalysed S–S, S–Si and S–B bond forming reactions

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Article information

DOI
https://doi.org/10.1039/C3CC43145B
Article type
Communication
Submitted
28 Apr 2013
Accepted
16 May 2013
First published
23 May 2013

Chem. Commun., 2013,49, 5829-5831

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Efficient ruthenium-catalysed S–S, S–Si and S–B bond forming reactions

J. A. Fernández-Salas, S. Manzini and S. P. Nolan, Chem. Commun., 2013, 49, 5829 DOI: 10.1039/C3CC43145B

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