Ab initio calculations predict planar transition states for bowl-to-bowl inversions in corannulene, ethenocorannulene and semibuckminsterfullerene with barriers of 14.4, 34.4 and ca. 74 kcal mol–1, (1 cal = 4.184 J), respectively, but a non-planar transition states for 1,2-dihydrocorannulene with a barrier of 10.9 kcal mol–1.
A. Sygula and P. W. Rabideau, J. Chem. Soc., Chem. Commun., 1994, 1497 DOI: 10.1039/C39940001497
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...