SCHEDULED MAINTENANCE
Thermolysis of adducts formed from tricarbonyl(vinylketene)iron(0) complexes and alkynes leads to either cyclopentenediones or phenols and its outcome is controlled by the electronic properties of the C-1 substituent of the adduct; the phenols may be synthesised directly and regioselectively from tricarbonyl(vinylketene)iron(0) complexes and electron-rich alkynes.
K. G. Morris, S. P. Saberi and S. E. Thomas, J. Chem. Soc., Chem. Commun., 1993, 209 DOI: 10.1039/C39930000209
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