Issue 3, 1991
From the journal:

Journal of the Chemical Society, Chemical Communications

Selective insertion of mercury(II) halides into the ruthenium–mercury bonds of trinuclear Ru2Hg clusters

Javier A. Cabeza,   José M. Fernández-Colinas,   Santiago García-Granda,   Víctor Riera  and  Juan F. Van der Maelen  

Abstract

The complex [Ru2(µ-dan)(CO)4(PPri3)2]1(H2dan = naphthalene-1,8-diamine) reacts with HgX2(X = Cl, Br or I) to give the trinuclear clusters [(1)HgX2] which react with HgZ2(Z = Cl, Br or I) to form the insertion products [(1)Hg(µ-Z)2HgX2] only when Z is more electronegative than X, otherwise the addition products [(1)Hg(µ-X)2HgZ2] are obtained; the X-ray structure of [(1)Hg(µ-Cl)2HgCl2] has been determined.

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Article information

DOI
https://doi.org/10.1039/C39910000168
Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 168-170

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Selective insertion of mercury(II) halides into the ruthenium–mercury bonds of trinuclear Ru2Hg clusters

J. A. Cabeza, J. M. Fernández-Colinas, S. García-Granda, V. Riera and J. F. Van der Maelen, J. Chem. Soc., Chem. Commun., 1991, 168 DOI: 10.1039/C39910000168

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