Issue 20, 1989

Studies of the synthesis, structure, and reactivity of a tetranuclear mixed-metal imido cluster, (η5-C5H5)WRu3(CO)9(µ-NPh)(C[triple bond, length half m-dash]CPh)

Abstract

The title complex (η5-C5H5)WRu3(CO)9(µ-NPh)(C[triple bond, length half m-dash]CPh), containing a bridging imido ligand and a µ42-acetylide ligand, has been prepared by means of the condensation between (η5-C5H5)W(CO)3C[triple bond, length half m-dash]CPh and Ru3(CO)103-NPh), and its reactions with dihydrogen and disubstituted alkyne ligands are presented; the products have been fully characterized by spectroscopic methods and X-ray diffraction studies for two complexes.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 1540-1543

Studies of the synthesis, structure, and reactivity of a tetranuclear mixed-metal imido cluster, (η5-C5H5)WRu3(CO)9(µ-NPh)(C[triple bond, length half m-dash]CPh)

Y. Chi, D. Hwang, S. Chen and L. Liu, J. Chem. Soc., Chem. Commun., 1989, 1540 DOI: 10.1039/C39890001540

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