Issue 24, 1987
From the journal:

Journal of the Chemical Society, Chemical Communications

The Aza-di-π-methane rearrangement of O-acetyl 2,2-dimethyl-4,4-diphenylbut-3-enal oxime

Diego Armesto,   William M. Horspool  and  Fernando Langa  

Abstract

The photochemical reaction of O-acetyl 2,2-dimethyl-4,4-diphenylbut-3-enal oxime is described: the reaction yields two cyclopropane derivatives, O-acetyl 3,3-dimethyl-2,2-diphenylcyclopropane carboxaldehyde oxime as the primary photoproduct, formed by an aza-di-π-methane reaction previously unobserved in such compounds, and 1-cyano-3,3-dimethyl-2,2-diphenylcyclopropane formed by thermal elimination of acetic acid from the primary product.

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Article information

DOI
https://doi.org/10.1039/C39870001874
Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1874-1875

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The Aza-di-π-methane rearrangement of O-acetyl 2,2-dimethyl-4,4-diphenylbut-3-enal oxime

D. Armesto, W. M. Horspool and F. Langa, J. Chem. Soc., Chem. Commun., 1987, 1874 DOI: 10.1039/C39870001874

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