Issue 23, 1987
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and characterisation of [VS4(CuPPh3)5(CuCl)Cl2]·CH2Cl2; a compound containing a tetrahedral VvS4 core encapsulated by an octahedral array of copper(I) atoms

Colin D. Scattergood,   Philip G. Bonney,   Jamie M. Slater,   C. David Garner  and  William Clegg  

Abstract

Reaction between [NH4]3[VS4], [NEt4]Cl, CuCl, and PPh3 in CH2Cl2 has led to the formation of [VS4(CuPPh3)5(CuCl)Cl2] which contains a hitherto unrecognised type of mixed metal sulphur cluster, consisting of a tetrahedral VVS4 core bound to an octahedral array of CuI atoms.

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Article information

DOI
https://doi.org/10.1039/C39870001749
Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1749-1750

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Synthesis and characterisation of [VS4(CuPPh3)5(CuCl)Cl2]·CH2Cl2; a compound containing a tetrahedral VvS4 core encapsulated by an octahedral array of copper(I) atoms

C. D. Scattergood, P. G. Bonney, J. M. Slater, C. D. Garner and W. Clegg, J. Chem. Soc., Chem. Commun., 1987, 1749 DOI: 10.1039/C39870001749

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