Issue 23, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

The synthesis and X-ray structural characterisation of the first mixed alkali metal organonitrogen molecular cluster LiNa3[O[double bond, length half m-dash]P(NMe2)3]3[N[double bond, length half m-dash]C(NMe2)2]4

William Clegg,   Robert E. Mulvey,   Ronald Snaith,   Gerald E. Toogood  and  Kenneth Wade  

Abstract

A mixed alkali metal guanidino complex LiNa3[O[double bond, length half m-dash]P(NMe2)3]3[N[double bond, length half m-dash]C(NMe2)2]4(1), the first compound of its type, has been synthesised from BunLi, BunNa, O[double bond, length half m-dash]P(NMe2)3, and HN[double bond, length half m-dash]C(NMe2)2; an X-ray crystallographic study shows it to be a cubane-type cluster built up of novel µ3-N–LiNa2 and µ3-N–Na3 pyramids though additional Li ⋯ H–C interactions are indicated.

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Article information

DOI
https://doi.org/10.1039/C39860001740
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1740-1742

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The synthesis and X-ray structural characterisation of the first mixed alkali metal organonitrogen molecular cluster LiNa3[O[double bond, length half m-dash]P(NMe2)3]3[N[double bond, length half m-dash]C(NMe2)2]4

W. Clegg, R. E. Mulvey, R. Snaith, G. E. Toogood and K. Wade, J. Chem. Soc., Chem. Commun., 1986, 1740 DOI: 10.1039/C39860001740

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