Calculated energetics of rearrangement and fragmentation on the S0 surface of thioformaldehyde
Abstract
Calculation of stationary points on the S0 Surface of Thioformaldehyde corresponding to loss of H2, isomerisation to thiohydroxycarbene, and to the formation of radical products support the contention that photodissociation in not an important decay process for the 1A2(S1) state of H2CS.