Issue 18, 1982
From the journal:

Journal of the Chemical Society, Chemical Communications

Photochemically inudced chelate ring expansion and hydrolysis reactions: X-ray crystal structures of [W{PPh2OC(Ph)[double bond, length half m-dash]CHPPh2}(CO)4] and [W(PPh2OH)(PPh2CH2COPh)(CO)4]

Subhi Al-Jibori,   Michael Hall,   Alan T. Hutton  and  Bernard L. Shaw  

Abstract

Light of intensity normally found in a laboratory transforms the 4-membered ring chelate [W{PPh2CH(COPh)PPh2}(CO)4] into the 6-membered ring chelate [W{PPh2OC(Ph)[double bond, length half m-dash]CHPPh2}(CO)4] and thence into a hydrolysis product [W(PPh2OH)(PPh2CH2COPh)(CO)4]; neither reaction occurs in the absence of light.

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Article information

DOI
https://doi.org/10.1039/C39820001069
Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 1069-1071

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Photochemically inudced chelate ring expansion and hydrolysis reactions: X-ray crystal structures of [W{PPh2OC(Ph)[double bond, length half m-dash]CHPPh2}(CO)4] and [W(PPh2OH)(PPh2CH2COPh)(CO)4]

S. Al-Jibori, M. Hall, A. T. Hutton and B. L. Shaw, J. Chem. Soc., Chem. Commun., 1982, 1069 DOI: 10.1039/C39820001069

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