Issue 1, 1982

Inter-relationships in molybdenocene dimer chemistry: a convenient synthesis of bis-η-cyclopentadienyldichloromolybdenum

Abstract

The dimers [η-C5H5)2HMo{µ-(η1:η5-C5H4)}Mo(η-C5H5)] and [(η-C5H5)(CO)Mo-µ-(η5:η1-C5H4)Mo(Co)2(η-C5H5] have been prepared from [Mo2(O2CMe)4] and characterised by crystal structure determination; the former dimer reacts readily with aqueous hydrochloric acid forming the dichloro-monomer [Mo(η-C5H5)2Cl2].

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 30-31

Inter-relationships in molybdenocene dimer chemistry: a convenient synthesis of bis-η-cyclopentadienyldichloromolybdenum

M. L. H. Green, M. L. Poveda, J. Bashkin and K. Prout, J. Chem. Soc., Chem. Commun., 1982, 30 DOI: 10.1039/C39820000030

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